Pace bowlers Sam Curran and Tymal Mills have also been added to the ICC Rest of the World XI team.
England limited-overs captain Eoin Morgan expects a "young and hungry" Australia will be "galvanised" by the ball-tampering scandal that rocked world cricket when the old rivals meet in a one-day global series next month.
England ODI squad (for Scotland game): Eoin Morgan (capt), Moeen Ali, Jonny Bairstow (wk), Sam Billings, Alex Hales, Liam Plunkett, Adil Rashid, Joe Root, Jason Roy, Ben Stokes, David Willey, Chris Woakes, Mark Wood.
The 26-year-oldwicketkeeper-batsman has played 13 one-dayers and 17 Twenty20 Internationals, and 142 T20s overall. "It's not a huge concern, it's one that hopefully we can manage after a week when the swelling goes down", he said. The T20I takes place on May 31 and all the proceeds from the match will be used to redevelop stadiums in the Caribbean damaged due to hurricanes past year.
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Andy Flower, the England and Wales Cricket Board's stand-in director, said on the ICC's official website: "It is not a bad crack but it is bad enough to keep him out of tomorrow's Middlesex game and the World XI game".
The England skipper was named in a 13-man squad to face Scotland and also a 14-strong line-up for the five clashes with Australia, that starts at The Oval on June 13.
Morgan was set to captain the World XI in a charity match against the West Indies at Lord's on Thursday which is being held to raise funds for stadiums in Dominica and Anguilla damaged by hurricanes that swept through the Caribbean past year.
That put him out of the Hurricane Relief T20 Challenge, and Shahid Afridi has since taken over as captain with Sam Billings replacing Morgan in the ICC World XI squad.
Other names in the World XI squad include Rashid Khan, Adil Rashid and India wicket-keeper Dinesh Karthik.